Steel from Wuppermann with maximum corrosion protection

Wuppermann's heat-to-coat galvanizing process offers highest corrosion protection with lowest CO2 emissions

Wuppermann's heat-to-coat hot-dip galvanising process differs in process from other methods in which steel is galvanised - i.e. protected against corrosion. In addition to significantly lower CO2 emissions, this process also scores with other advantages in terms of resource consumption, properties during further processing and corrosion protection.

Properties of steel

Steel is resistant, covers a wide toughness range and can be customized to meet customer requirements. But without reliable corrosion protection, it quickly loses the positive properties that make it so successful as a building material. Steel corrodes in the atmosphere, in water and in the soil. The result of corrosion is the formation of red rust, which, in addition to visual disadvantages in visible parts, can lead to component failure.

Protecting steel from corrosion

To counteract this, steel is coated. Among the various options for corrosion protection, finishing steel with zinc is the most reliable and effective. The most industrially significant method is hot-dip galvanising, in which either ready-formed steel components are discontinuously immersed in a molten bath and galvanised, or steel strips pass through a zinc bath continuously after they have been appropriately thermally pretreated. The conditions under which the thermal treatment must take place are determined by the condition of the starting material, whether it is cold-rolled strip with a strongly consolidated microstructure without any appreciable forming capacity or hot-rolled strip with already useful mechanical properties for further processing. In this respect, the following three hot-dip galvanising processes can be distinguished:

- Piece galvanising (discontinuous),
- cold strip galvanising (continuous),
- hot strip galvanising, including the Wuppermann heat-to-coat process (continuous).

 The heat-to-coat process is explained using the example of the hot strip galvanising plant of the Wuppermann Group in Hungary, which, in addition to normal zinc coatings, can also apply the new zinc-aluminum-magnesium alloy to steel strip by means of an alternating spot system (see figure 1).

The following applies to all three processes: The thicker the zinc coating, the higher the corrosion protection. The level of corrosion protection required depends on the environmental conditions at the site of use of the subsequent component. The processes usually work with the following zinc coating thicknesses per side:

Process                        Zinc coating thickness min.     Zinc coating thickness max.
Piece galvanisation       50 µm                                          85 µm
Cold strip galvanising     5 µm                                          55 µm
Hot strip galvanising       5 µm                                          85 µm

The areas of application of piece-galvanised and strip-galvanised steel differ for the most part, but there are also overlaps, especially where galvanised profiles with high zinc layers are used. For example, crash barriers for vehicle restraint systems or substructures for photovoltaic systems can be manufactured both with batch galvanisation and on the basis of hot strip galvanisation. Nevertheless, the following introduction to the heat-to-coat process essentially focuses on the comparison with the more similar cold strip galvanising process.

The process sequence of the strip galvanising methods in comparison (see figure 2)

In the case of cold-rolled strip, the strips are first recrystallising annealed at high temperatures in a large annealing furnace directly upstream of the hot-dip galvanising process. In this process, they regain their forming capacity and achieve very special narrow mechanical properties, which are primarily required in the automotive industry. In contrast to conventional strip galvanising lines, the Wuppermann process does not require an annealing furnace (see figure 1). Apart from the obvious advantages - the reduced costs in acquisition as well as maintenance - the lack of an annealing furnace results in further positive effects. Without an annealing furnace, Wuppermann has more flexibility in the operation of the plant. If necessary, strip galvanising can be shut down, for example at the weekend, and then restarted without any significant loss of quality. This leads to less scrap when restarting and to lower personnel costs. Furthermore, the heat-to-coat process works with a much lower maximum temperature. When using cold-rolled strip, an annealing furnace is necessary to recrystallise the starting material. Depending on the steel grade, this takes place at temperatures from 650 to over 850°C. At Wuppermann, recrystallisation is not necessary due to the use of hot-rolled strip as the starting material - within the strip thickness spectrum comparable to cold-rolled strip. The maximum strip temperature is around 450°C. It only has to be high enough to achieve a reduction of the strip surface before immersion in the molten zinc. This leads to a considerably lower energy consumption.
In this context, the different energy sources that are used also play a major role. In contrast to standard plants, the heat-to-coat process does not use fossil fuels such as gas. Wuppermann only uses electricity to heat up the strip and therefore gets by with comparatively short ovens. Apart from the fact that these furnaces are cheaper to purchase, above all the energy consumption is significantly reduced, which again both minimises costs and benefits the environment.

Definition of the zinc layer, corrosion protection and further processing

On hot strip, even high zinc layer thicknesses of up to 85 µm per side can be produced reproducibly, uniformly and precisely over strip width and length, and the structure of the zinc layer is still homogeneous and free of ZnFe alloy phases (see Figure 3). The melting baths in continuous strip galvanising are low alloyed with aluminium to ensure the adhesive bond of the layer with the base material. Furthermore, it should be mentioned that no alloying measures are taken to influence the crystal structure of the zinc layer.
These zinc coatings have a very good adhesion to the base material and also withstand more complex forming operations. The high level of corrosion protection is also maintained and, for example, profiles can be produced from hot-dip galvanised hot-rolled strip that are suitable for bright use outdoors.

Production portfolio

The heat-to-coat process enables cost-effective and environmentally compatible processing of hot-rolled strip with a thickness of 1 to 6 mm and a maximum width of 1,650 mm. The main materials used are steels for cold forming and deep drawing, structural steels, and high-strength and low-alloy steels. Coatings of up to 85 µm on one side or 1,200 g/m² on both sides can be achieved. In contrast to the batch galvanising process, the continuous galvanising process allows steel strips to be produced with different zinc coating thicknesses on different sides, the so-called differential galvanising. This is essential for galvanised steel pipes, for example, as the necessary coating thicknesses can be applied on the outside and inside due to the different corrosion requirements. This saves both resources and costs and thus has a high customer benefit.

Environmental impact

The described differences in process design also lead to a better CO2 footprint of Wuppermann's heat-to-coat process. Recently, the significantly lower CO2 emissions were confirmed accordingly by the Fraunhofer Institute for Environmental, Safety and Energy Technology (UMSICHT). Further information on the study can be found here.

 

Figure 1: The heat-to-coat process in detail using the example of the Wuppermann Hungary kft. plant in Györ, Hungary. (Source: Wuppermann AG)

Figure 2: Differences between the Wuppermann "Heat-to-coat" process and the reference process cold strip galvanising (Source: Fraunhofer Institut / Wuppermann AG

Figure 3: Structure of the zinc layer: homogeneous and free of ZnFe alloy phases (Source: Wuppermann Engineering GmbH)